Rheological Behavior of Concentrated Monodispersed Colloidal Suspensions

Local transient rheological behavior of concentrated suspensions

The rheological behavior of concentrated colloidal dispersions

A simple model for the rheological behavior of concentrated colloidal dispersions is developed. For a suspension of Brownian hard spheres there are two contributions to the macroscopic stress: a hydrodynamic and a Brownian stress. For small departures from equilibrium, the hydrodynamic contribution is purely dissipative and gives the high-frequency dynamic viscosity. The Brownian contribution h...

Dielectric response of concentrated colloidal suspensions

The determination of the low-frequency ~typically 0–1 MHz! dielectric dispersion of colloidal suspensions may become an electrokinetic tool of wider use if the accuracy of experimental data can be improved and if trustable theories, available for a wide range of situations, are made available. In the present work, we focus on the latter aspect: Since the dielectric constant of the suspensions i...

Polyelectrolyte Effects on the Rheological Properties of Concentrated Cement Suspensions

Polyelectrolyte species, known as superplasticizers, dramatically affect the rheological properties of dense cement suspensions. We have studied the influence of sulfonated naphthalene formaldehyde condensate (SNF) and carboxylated acrylic ester (CAE) grafted copolymers of varying molecular architecture on the surface (e.g., adsorption behavior and zeta potential) and rheological properties of ...

Structure and dynamics studies of concentrated micrometer-sized colloidal suspensions.

We present an experimental study of the structural and dynamical properties of concentrated suspensions of different sized polystyrene microspheres dispersed in glycerol for volume fraction concentrations between 10% and 20%. The static structure, probed with ultrasmall-angle X-ray scattering, shows a behavior very similar to that of hard spheres. The equilibrium dynamics is probed with ultrasm...